Preheat the grill, grill pan, or a very hot cast iron skillet. Wash the bell peppers, cut each in half lengthwise, and remove the seeds and white membranes. Brush the skin with a thin layer of canola oil (use a brush or your hand) to prevent burning. Place the peppers skin side down on the heated surface and grill for 6-8 minutes, until the skin is well browned and starts to blacken. Turn and grill the other side for 4-6 minutes. The skin should be loose and partially cracked.
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