Wash the rhubarb, trim the ends, and cut the stalks into pieces 2-3 cm long. In a small pot, combine apple cider vinegar (100 ml), sugar (30 g), salt (2 g), and black pepper (2 g). Heat over medium heat until the sugar dissolves (about 2-3 minutes), stirring with a wooden spoon. Remove from heat and pour the hot marinade over the chopped rhubarb. Let it sit for at least 20 minutes at room temperature, then refrigerate for 10-15 minutes — the rhubarb should soften while retaining its shape and pink color.
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